Electronic information age, so that the mobile power needs are growing rapidly. As the lithium-ion battery with high voltage, an important advantage of high capacity and long cycle life, safety performance is good, so that the portable electronic devices, electric vehicles, space technology, defense industry, and many have broad application prospects, becoming the last few years of extensive public attention in research focus [1] [2] [3]. The mechanism of lithium-ion battery general analysis that the lithium-ion battery as a chemical power source, refer to two separate and de-embedding can be reversibly lithium intercalation compounds as positive and negative ion secondary battery constituted. When the battery is charging, the lithium-ion from the cathode in the de-embedded, embedded in the cathode, discharge the contrary.
Lithium-ion battery is physics, materials science and chemistry of the crystallization of interdisciplinary research. Lithium-ion ibm laptop battery involved in the physical mechanism, is currently being embedded in solid-state physics to explain the physical, the embedding (intercalation) is movable object particles (molecules, atoms, ions) reversible embedded in the main body with the right size of the lattice The network space point. Electron transport lithium-ion battery cathode and anode materials are mixed ionic and electronic conductor embedded compound. Electronics can only be positive and negative material movement [4] [5] [6]. Embedded in a wide range of known compounds, object particles can be molecules, atoms or ions. In the embedded ions, requested by the main structure for charge compensation in order to maintain electrical neutrality. Charge compensation can be the main material can be achieved with changes in the structure, electrical conductivity before and after the embedded subject to change. Lithium-ion battery electrode materials can exist stably in the air is closely related with this feature. Intercalation compound only to meet the structural changes in reversible and are able to change the structure in order to compensate for the charge, as lithium-ion battery electrode materials.
Control the performance of lithium-ion IBM thinkpad t40 battery key material – Battery Chiang Kai-shek negative active material is the key to this technology, it is the consensus of the researchers at home and abroad.
A cathode material performance and the general preparation method
Positive characterization of ion transport in the nature of the important parameter is the chemical diffusion coefficient, usually, the positive active material in lithium-ion diffusion coefficients are relatively low. Cathode materials for lithium insertion into or from the working-class de-embedded material, accompanied by changes in crystal phase. Therefore, the lithium-ion batteries require a very thin film electrodes, usually tens of microns in order of magnitude. Cathode Material Lithium compounds are lithium-ion battery Lithium-ion temporary storage containers. In order to obtain a high single thinkpad t41 battery voltage, tend to choose high electrical potential of the lithium intercalation compounds. Cathode material should be met:
1) In the required charge-discharge potential within the electrolyte solution has the electrochemical compatibility;
2) moderate kinetics of electrode process;
3) a high degree of reversibility;
4) full of state of lithium in the air stability.
The study focused on layered LiMO2 hot and spinel-type structure of compounds and composite LiM2O4 two kinds of M (M is Co, Ni, Mn, V and other transition metal ions) is similar to the electrode materials. As a lithium-ion thinkpad t42 battery cathode material, Li + ions in the process of de-embedding and embedding structural changes in the extent and reversibility determine the stability of the battery charge and discharge of repetition. Preparation of cathode material, its material properties and synthesis of process conditions will have an impact on the final structure. A variety of promising cathode material, there is the use of the cycle of decay in capacitance, which is a research priority. Have been commercialized cathode materials Li1-xCoO2 (01) solid-phase method generally used in lithium carbonate and other lithium salts and cobalt or nickel compounds, lapping compounds, after mixing to sintering reaction [10]. Advantage of this method is to process simple and easy to get raw materials belonging to the early development of lithium-ion battery development and production has been extensively studied approach, the more mature foreign technology; disadvantage is that the prepared cathode materials for electric capacity is limited, poor mixing of raw materials, preparation of materials performance, stability, good, quality, consistency between batches and the batch difference.
2) The complex method using organic complex preparation containing the first lithium-ion and cobalt or vanadium ion complex precursor, and then sintering. This method has the advantage of molecular-scale mixing, material uniformity and performance, good stability, cathode materials, high capacitance compared to solid-state method, and foreign has been testing lithium-ion thinkpad t43 battery used for the industrialization of methods, technologies not mature, yet few reported. 3) sol-gel method using the last century, 70 years since the development of
Preparation of ultrafine particles to the method of preparation of cathode material, the method has the advantages of the complex law, but also prepared the capacitance of the electrode materials have a greater increase being at home and abroad belong to the rapid development of methods. The disadvantage is high cost of technology is a development stage [11].
4) ion exchange process such as Armstrong prepared by using ion-exchange LiMnO2, won the reversible discharge capacity of up to 270mA • h / g high-value, this method for studying the new hot spot, which has the electrode system, thinkpad r50 battery,stable performance, high capacity electrical characteristics of . However, re-crystallization process involves evaporation of solution and time-consuming steps such as license fees, there is a considerable distance away from practical use.
Cathode materials research literature can be seen from abroad, its power capacity to an annual 30 ~ 50mA • h / g at the rate of growth and development tend to become smaller and smaller-scale micro-structure, while increasing power capacity of lithium intercalation compounds and raw materials to the nano-scale advance, on the structure of lithium intercalation compounds, theoretical research has made some progress, but its development in the theory is still evolving. Trouble in this area increases the capacity of lithium thinkpad r51 battery power and recycling capacity fade problem, researchers have proposed to add other components to overcome the method [12] [13] [14] [15] [16] [17]. But for now, these methods have not thoroughly studied the theory of the mechanism, leading Japanese scholars Yoshio.Nishi that in the past decade, little substantive progress in this field [1], an urgent need for further study.
2 Anode material properties and the general preparation method
The conductivity of anode materials are generally higher, select potential as close as possible potentials can be embedded lithium-lithium compounds, such as various carbon materials and metal oxides. Reversibly de-embedded embedded anode material for lithium-ion requires:
1) In the lithium-ion IBM fru 08k8193 intercalation reaction in the free energy change is small;
2) lithium-ion solid-state structures in the anode have a high proliferation rate;
3) highly reversible intercalation reaction;
4) have a good electrical conductivity;
5) The thermodynamic stability, while not react with the electrolyte.
Research focused on carbon materials and has a special structure of other metal oxides. Graphite, soft carbon, medium-carbon microspheres have been in the country there are development and research, hard carbon, carbon nanotubes, buckyballs C60 and other carbon materials is being studied in [18] [19] [20] [21] [22] [23]. Japan’s Honda Researchand Development Co. , Ltd, K. Sato and other people use poly p-phenylene vinylene (Polyparaphenylene – PPP) of thermal decomposition products PPP-700 (to a certain heating rate heating PPP to 700 ℃, and the heat some time to be a product of the pyrolysis) as a negative,IBM 92p1060, the reversible capacity of up to 680mA • h / g. U.S. MIT, MJMatthews reports PPP-700 lithium storage capacity (Storagecapacity) up to 1170mA • h / g. If the lithium storage capacity of 1170mA • h / g, with an increase in the amount of lithium insertion, thereby improving lithium-ion battery performance, I believe that future research will focus on the smaller nano-scale micro-structure of lithium intercalation. Study of carbon anode is almost the same time, looking for potential and Li + / Li potential similar to other anode material has been taken seriously. Lithium-ion batteries used in the carbon materials surviving in two aspects:
1) Voltage lags, that is, lithium intercalation IBM 08k8214 reaction in between 0 ~ 0.25V (relative to Li + / Li) and the de-embedded response occurred at about in the 1V;
2) Cycle the capacity decreased gradually, generally after 12 to 20 cycles, the capacity dropped to 400 ~ 500mA • h / g.
Theory also relies on the further deepening of a variety of high-purity, structural regularity of raw materials and carbon materials Preparation and Characterization of a more effective method of building. Fuji has developed a new type of lithium-ion battery anode materials for tin-based composite oxide, in addition to the existing research has focused on a number of metal oxides, the mass ratio of energy than the carbon anode materials increased substantially. Such as SnO2, WO2, MoO2, VO2, TiO2, LixFe2O3, Li4Ti5O12, Li4Mn5O12, etc. [24], but not as sophisticated carbon electrode. Lithium in carbon IBM 08k8195 materials, reversible high-storage mechanism in the main formation mechanism of lithium Li2 molecule, multi-layered lithium mechanism, mechanism of crystal lattice, elastic ball – elastic net model, layer – side-side – the surface of lithium storage mechanism of nano-graphite reservoir Li-ion mechanism, carbon – lithium – lithium hydrogen storage mechanism and the mechanism of pore. Graphite, as a kind of carbon materials, has long been found that it formed with the lithium-graphite intercalation compound (Graphite Intercalation Compounds) LiC6, but these theories is still in development stage. To overcome the difficulties of anode materials is also a question of capacity loop attenuation, but in literature we can see that preparation of high purity and regularity of the micro-structure of carbon anode materials is the development of a direction.